Complexometric titrations introduction the complete applications package at radiometer analytical, we put applications first. Xylem analytics germany distributes a large number of highquality analyzers and sensors through its numerous wellknown brands. In this procedure a stock solution of edta will be standardized. Complexometric titration edta, types of complexometric. Application of complexometric titration pdf download. In this chapter we will focus on the chemistry of one particular ligand, ethylenediaminetetraacetic acid edta.
In a complexometric titration, a solution containing the free metal ion of interest is titrated. To permit many metals to be titrated in alkaline solutions with edta, we use an auxiliary complexing agent. Edta, agno 3, na 2 s 2 o 3, ceso 4 2, nh 4 2 fe 2 so 4 2. Titration theory and practice the aim of this booklet is to explore titration from a historical, theoretical and practical point of view, dealing first with preset. Complexometric titrations are particularly useful for determination of a mixture of different metal ions in solution. Ethylene diamine tetra acetic acid edta, is a very important reagent for complex formation titrations. Pdf determination of the hardness of tap water using. Edta is a hexadentate ligand because of its competence to denote six pair of lonely electrons due to the formation of covalent bonds. The hardness of water is defined in terms of its content of calcium and magnesium ions. For the titration, the sample solution containing the calcium and magnesium ions is reacted with an excess of edta.
Titration handbook theory and practice of titration. Transfer 50 ml of tap water to four different erlenmeyer flasks. Edta called as ethylenediaminetetraacetic acid is a complexometric indicator consisting of 2 amino groups and four carboxyl groups called as lewis bases. Edta titration for determination of calcium and magnesium. Edta has been assigned the formula ii in preference to i since it has been obtained from measurements of the dissociation constants that two hydrogen atoms are probably held in the form of zwitter ions. Add 6 drops of indicator and 3 ml of buffer solution. Calcium analysis by edta titration one of the factors that establish the quality of a water supply is its degree of hardness. Ethylene diamine tetra acetic acid edta, is a very. In this experiment a solution of edta will be standardize by titration against a standard solution made from calcium carbonate, caco3. When you order one of our new generation of titration workstations with a dedicated application package, you have every. Edta titration conditions in this chapter were selected to prevent metal hydroxide precipitation at the chosen ph. The sulfate content of 28 water samples taken at 4 hydrographic stations in the baltic, was determined by indirect edta titration. In order to determine the equivalence point in titration of metal ions with edetic acid, it is necessary to use a suitable indicator that will react to the presence of free metal ions in solution.
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